That's because they made deals with content providers to sell you ebooks and audiobooks outside the US, and presumably they don't have those deals for Kindle Unlimited yet. Just because Amazon has the publisher's permission to sell you an ebook doesn't mean that they automatically have the publisher's permission to give that ebook to Kindle Unlimited subscribers.
See this explanation by author Charlie Stross: http://www.antipope.org/charlie/blog-static/2014/07/some-ram...