Like most geeks I have far too much self-doubt to consider a start-up alone. Every time I have an idea I can pick it apart technically in minutes in my mind (Dunning-Kruger effect).
Really, who needs online file synchronization when a USB key and rsync are perfectly fine!
I have some IaaS ideas I've been kicking around but they are all capital intensive. The only way I can make it financially feasible is to build my own servers. And with no SLA or warranties I would basically have to live at the datacenter.
http://startupchile.org/