Well, yes. But the expected deviation from the mean is still ≈7.07. And the probability that the outcome will be either 93/107 or 107/93 is (slightly) higher than the outcome being exactly 100.
So while those are two results (93/107 and 107/93), they really only count as two separate outcomes if you pre-specify that the first number is heads.
If instead you consider symmetries, where there are 2 ways to get 93/107 and only one wall to get 100/100, then you have more likelihood for the 93/107 outcome because you have two ways to get it.
I don't think that makes 100 / 100 the most likely result if you flip a coin 200 times. It's not about 100 / 100 vs. another single possible result. It's about 100 / 100 vs. NOT 100 / 100, which includes all other possible results other than 100 / 100.
Depends what you count as a result, I guess. "There is exactly N flips of a single kind" is also a viable definition, just as "The exact sequence of flips was x_0, x_1, ... x_199" is.
Why not go one abstraction further and go expected deviation from deviation? Probably the word "expected" plays a mind trick? "Expected" doesn't mean the probability increases, the easiest way to understand it is just by looking at the probability distribution function chart for coin tosses - you'll immediately see that mean has the highest chance of happenning, so exactly 100 is the most likely outcome