Individually, sure. But in an organization, the larger it is, the more probability that all of the features are being used approaches 1. Then you don't have a software issue anymore, you have a business workflow, retraining, or retooling issue.
Using multiple tiers of the same application is a good strategy.
And using partial MS Office and partial LibreOffice is also certainly an option, but whether it will be successful depends on an organization's workflow, because that introduces an additional interoperability risk which isn't an issue if everyone uses the same tool.
Most people only use a small percentage of functionality in any app.